Ethyl 2-(5-fluoro-3-methylsulfinyl-1-benzofuran-2-yl)acetate

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Ethyl 2-(5-fluoro-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate

In the title compound, C(13)H(13)FO(4)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The crystal structure exhibits four inter-molecular non-classical C-H⋯O hydrogen bonds. In addition, the crystal structure contains aromatic π-π inter-actions between the furan and benzene rings of adjacent mol-ecules [ce...

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5-Ethyl-3-(2-fluoro­phenyl­sulfon­yl)-2-methyl-1-benzofuran

In the title compound, C(17)H(15)FO(3)S, the 2-fluoro-phenyl ring makes a dihedral angle of 89.12 (8)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯O and C-H⋯π inter-actions.

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5-Fluoro-3-(3-fluoro­phenyl­sulfon­yl)-2-methyl-1-benzofuran

In the title compound, C(15)H(10)F(2)O(3)S, the 3-fluoro-phenyl ring makes a dihedral angle of 79.51 (6)° with the mean plane [r.m.s. deviation = 0.006 (2) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked by weak C-H⋯F and C-H⋯O hydrogen bonds. The crystal structure also exhibits slipped π-π inter-actions between the benzene and furan rings of neighbouring mol-ecules [centro...

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5-Ethyl-3-(3-fluoro­phenyl­sulfon­yl)-2-methyl-1-benzofuran

In the title compound, C(17)H(15)FO(3)S, the fluoro-phenyl ring makes a dihedral angle of 76.11 (5)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions.

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2-(4-Bromo­phen­yl)-5-fluoro-3-phenyl­sulfinyl-1-benzofuran

In the title compound, C(20)H(12)BrFO(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment; the phenyl ring is nearly perpendicular to this plane [dihedral angle = 86.98 (6)°]. The 4-bromo-phenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 1.56 (8)°. The crystal structure f...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809025938